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In vitro, high copper concentrations (0.40.6mM) have been shown to activate NFKB in HepG2 cells [24], and this activation appears crucial for cell survival under copper stress [26]

GSH accounts for about 95% of the total non-protein thiols within cells, with intracellular concentrations ranging from 0.5 to 10 mM, far surpassing the levels of free cysteine (3-4)